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Synthesis, Characterization and Reactivity of Ylidyne and μ-Ylido Complexes Supported by Scorpionato Ligands

This book explores the development of the first open-shell heavier tetrylidyne complexes featuring a tetrel-centered unpaired electron, and unprecedented metallatetrylidynes containing a multiply-bonded, linear-coordinated single heavier tetrel atom embedded between two metal centers. The chemistry...

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Detaylı Bibliyografya
Yazar: Ghana, Priyabrata (Yazar)
Müşterek Yazar: SpringerLink (Online service)
Materyal Türü: e-Kitap
Dil:İngilizce
Baskı/Yayın Bilgisi: Cham : Springer International Publishing : 2019.
Imprint: Springer,
Edisyon:1st ed. 2019.
Seri Bilgileri:Springer Theses, Recognizing Outstanding Ph.D. Research,
Konular:
Online Erişim:Full-text access
İçindekiler:
  • Introduction
  • Closed shell heavier tetrylidyne complexes of group 6 metals
  • Open-shell heavier tetrylidyne complexes of group 6 transition metals
  • Germylidyne mediated C-C coupling reaction of isonitriles - formation of an N-heterocyclic germylene
  • A new method for the synthesis of manganese tetrylidyne complexes
  • An open-shell manganese stannylidyne comprising of a tin-centered unpaired electron
  • µ-Ylido complexes
  • Chemistry of the metallatetrylidyne complexes
  • Plumbylidyne transfer reaction
  • Access to the first NHC-stabilized disilavinylidene
  • Summary and Outlook
  • Experimental Section.