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Multifunctional Molecular Magnets Based on Octacyanidometalates
This thesis demonstrates the novel magnetic functionalities in cyanido-bridged metal assemblies, and as such appeals to readers in the field of materials science. The utilization of octacyanidometalates as building blocks enables the observation of (i) photo-induced magnetization due to a light-indu...
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| Format: | e-Book |
| Language: | English |
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Singapore :
Springer Nature Singapore :
2017.
Imprint: Springer, |
| Edition: | 1st ed. 2017. |
| Series: | Springer Theses, Recognizing Outstanding Ph.D. Research,
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| Subjects: | |
| Online Access: | Full-text access |
| Summary: | This thesis demonstrates the novel magnetic functionalities in cyanido-bridged metal assemblies, and as such appeals to readers in the field of materials science. The utilization of octacyanidometalates as building blocks enables the observation of (i) photo-induced magnetization due to a light-induced spin-crossover in an iron octacyanidoniobate-based assembly, (ii) photo-induced magnetization with a two-step spin-crossover behavior in an iron octacyanidoniobate-based material, and (iii) the coexistence of super-ionic conductivity and metamagnetism in a manganese-octacyanoniobate system. These multi-functionalities are achieved by incorporating a spin-crossover moiety or a hydrogen-bonding network into a cyanido-bridged network structure with a strong magnetic interaction. In particular, in light-induced spin-crossover magnets, a magnetically non-ordered state can be altered to a magnetically ordered state by photo-irradiation, which is one of the attractive mechanisms for novel optical switching devices. |
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| Physical Description: | XIII, 89 p. 64 illus., 38 illus. in color. online resource. |
| ISBN: | 9789811061356 |
| ISSN: | 2190-5061 |
| DOI: | 10.1007/978-981-10-6135-6 |