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Milestones in Microwave Chemistry
This book looks back on thirty-five years of microwave (MW) chemistry and explains how the application of the MW technique became an integral part of R&D, eventually becoming recognized in industry. Further, it details how MW chemistry has undergone a dynamic development in the past three decade...
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| Diğer Yazarlar: | |
| Materyal Türü: | e-Kitap |
| Dil: | İngilizce |
| Baskı/Yayın Bilgisi: |
Cham :
Springer International Publishing :
2016.
Imprint: Springer, |
| Edisyon: | 1st ed. 2016. |
| Seri Bilgileri: | SpringerBriefs in Green Chemistry for Sustainability,
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| Online Erişim: | Full-text access |
| Özet: | This book looks back on thirty-five years of microwave (MW) chemistry and explains how the application of the MW technique became an integral part of R&D, eventually becoming recognized in industry. Further, it details how MW chemistry has undergone a dynamic development in the past three decades, one driven by the advent of increasingly sophisticated professional MW reactors in place of the kitchen MW ovens used in earlier years. A major part of the book shows how substitutions, esterifications, amidations, hydrolyses, alkylations, eliminations, dehydrations, condensations, cyclizations, C-C couplings and the modification of heterocycles can be performed advantageously under MW irradiation, as the reaction times are shorter, while the selectivity and yields are higher; it also explains why in most cases, the reactions can be performed under solvent-free conditions. MW irradiation within the sphere of organophosphorus chemistry is showcased and typical reactions, such as the direct derivatization of phosphinic acids, alkylating esterifications, Diels-Alder reactions, the inverse Wittig-type reaction, fragmentations, the Arbuzov reaction, the synthesis of α-hydroxyphosphonates and α-aminophosphonates (the Kabachnik-Fields condensation), deoxygenations and P-C coupling reactions are described under MW conditions. In closing, the advantages of MW chemistry such as faster reactions and the possibility of simplifying the catalytic systems are addressed. |
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| Fiziksel Özellikler: | IX, 110 p. 144 illus., 4 illus. in color. online resource. |
| ISBN: | 9783319306322 |
| ISSN: | 2452-185X |
| DOI: | 10.1007/978-3-319-30632-2 |