New Carbon-Carbon Coupling Reactions Based on Decarboxylation and Iron-Catalyzed C-H Activation

This thesis presents the latest developments in new catalytic C-C bond formation methods using easily accessible carboxylate salts through catalytic decarboxylation with good atom economy, and employing the sustainable element iron as the catalyst to directly activate C-H bonds with high step effici...

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Bibliographic Details
Main Author: Shang, Rui (Author)
Corporate Author: SpringerLink (Online service)
Format: e-Book
Language:English
Published: Singapore : Springer Nature Singapore : Imprint: Springer, 2017.
Edition:1st ed. 2017.
Series:Springer Theses, Recognizing Outstanding Ph.D. Research,
Subjects:
Organometallic chemistry .
Catalysis.
Chemistry, Physical and theoretical.
Organometallic Chemistry.
Theoretical Chemistry.
Online Access:Full-text access
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Table of Contents:
  • Introduction to Carbon-Carbon Coupling Reactions Based on Decarboxylation and Iron-Catalyzed C-H Activation
  • Part I New Carbon-Carbon Bond Formation Methodologies Based on Decarboxylation
  • Transition-Metal-Catalyzed Decarboxylation and Decarboxylative Cross-Couplings
  • Palladium-Catalyzed Decarboxylative Coupling of Potassium Oxalate Monoester with Aryl and Alkenyl Halides
  • Synthesis of Polyfluorobiaryls via Copper-Catalyzed Decarboxylative Couplings of Potassium Polyfluorobenzoates with Aryl Bromides and Iodides
  • Palladium-Catalyzed Decarboxylative Couplings of Potassium Polyfluorobenzoates with Aryl Bromides, Chlorides and Triflates
  • Construction of C(sp3)-C(sp2) Bonds via Palladium-Catalyzed Decarboxylative Couplings of 2-(2-Azaaryl)acetate Salts with Aryl Halides
  • Synthesis of α-Aryl Nitriles and α-Aryl Acetate Esters via Palladium-Catalyzed Decarboxylative Couplings of α-Cyano Carboxylate Salts and Malonate Monoester Salts with Aryl Halides
  • Palladium-Catalyzed Decarboxylative Couplings of Nitrophenyl Acetate Salts and Its Derivatives with Aryl Halides
  • Palladium-Catalyzed Decarboxylative Benzylation of α-Cyano Aliphatic Carboxylate Salts with Benzyl Electrophiles
  • Part II New Carbon-Carbon Bond Formation Methodologies Based on Iron-Catalyzed C-H Activation
  • Recent Develpments of Iron-Catalyzed Directed C-H Activation/C-C Bond Formation Reactions.-β-Arylation of Carboxamides via Iron-Catalyzed C(sp3)-H Bond Activation
  • Iron-Catalyzed C(sp2)-H and C(sp3)-H Bond Functionalization with Organoboron Compounds.

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