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On the Catalytic Efficacy of Low-Oxidation State Group 14 Complexes
This outstanding thesis describes a detailed investigation into the use of low-oxidation-state group 14 complexes in catalysis, developed at the cutting edge of inorganic and organometallic chemistry. It includes the preparation of a number of landmark compounds, some of which challenge our current...
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| Format: | e-Book |
| Language: | English |
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Cham :
Springer International Publishing :
2017.
Imprint: Springer, |
| Edition: | 1st ed. 2017. |
| Series: | Springer Theses, Recognizing Outstanding Ph.D. Research,
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| Online Access: | Full-text access |
| Summary: | This outstanding thesis describes a detailed investigation into the use of low-oxidation-state group 14 complexes in catalysis, developed at the cutting edge of inorganic and organometallic chemistry. It includes the preparation of a number of landmark compounds, some of which challenge our current understanding of metal-metal bonding and low-oxidation-state main group chemistry. Among the many highlights of this thesis, the standout result is the development of the first well-defined, low- oxidation-state main group hydride systems as highly efficient catalysts in the hydroboration of carbonyl substrates, including carbon dioxide, which are as efficient as those observed in more traditional, transition-metal catalyses. These results essentially define a new subdiscipline of chemistry. |
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| Physical Description: | XIX, 243 p. 170 illus., 59 illus. in color. online resource. |
| ISBN: | 9783319518077 |
| ISSN: | 2190-5061 |
| DOI: | 10.1007/978-3-319-51807-7 |