Yüklüyor…
On the Catalytic Efficacy of Low-Oxidation State Group 14 Complexes
This outstanding thesis describes a detailed investigation into the use of low-oxidation-state group 14 complexes in catalysis, developed at the cutting edge of inorganic and organometallic chemistry. It includes the preparation of a number of landmark compounds, some of which challenge our current...
| Yazar: | |
|---|---|
| Müşterek Yazar: | |
| Materyal Türü: | e-Kitap |
| Dil: | İngilizce |
| Baskı/Yayın Bilgisi: |
Cham :
Springer International Publishing :
2017.
Imprint: Springer, |
| Edisyon: | 1st ed. 2017. |
| Seri Bilgileri: | Springer Theses, Recognizing Outstanding Ph.D. Research,
|
| Konular: | |
| Online Erişim: | Full-text access |
| Özet: | This outstanding thesis describes a detailed investigation into the use of low-oxidation-state group 14 complexes in catalysis, developed at the cutting edge of inorganic and organometallic chemistry. It includes the preparation of a number of landmark compounds, some of which challenge our current understanding of metal-metal bonding and low-oxidation-state main group chemistry. Among the many highlights of this thesis, the standout result is the development of the first well-defined, low- oxidation-state main group hydride systems as highly efficient catalysts in the hydroboration of carbonyl substrates, including carbon dioxide, which are as efficient as those observed in more traditional, transition-metal catalyses. These results essentially define a new subdiscipline of chemistry. |
|---|---|
| Fiziksel Özellikler: | XIX, 243 p. 170 illus., 59 illus. in color. online resource. |
| ISBN: | 9783319518077 |
| ISSN: | 2190-5061 |
| DOI: | 10.1007/978-3-319-51807-7 |