Functionalization of Carborane via Carboryne Intermediates

This thesis focuses on the development of new methods of functionalizing carboranes using o-carboryne intermediates. Functional carboranes are now finding a broad range of applications, including organic synthesis, drug design, polymers, catalysis, metal−organic frameworks, electronic devices and mo...

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Bibliographic Details
Main Author: Zhao, Da (Author)
Corporate Author: SpringerLink (Online service)
Format: e-Book
Language:English
Published: Singapore : Springer Nature Singapore : 2016.
Imprint: Springer,
Edition:1st ed. 2016.
Series:Springer Theses, Recognizing Outstanding Ph.D. Research,
Subjects:
Chemistry, Organic.
Physical chemistry.
Catalysis.
Organic Chemistry.
Physical Chemistry.
Online Access:Full-text access
Table of Contents:
  • Introduction
  • Regioselective Insertion of ο-Carborynes into α-C−H Bond of Tertiary Amines
  • Synthesis of Carborane-Functionalized Heterocycles: Dearomative [2 + 2] Cycloaddition and sp2 C-H Insertion Reaction
  • Reaction of ο-Carboryne with Nitrones: A Formal [5 + 2] Cycloaddition
  • 1,3-Dehydro-ο-Carborane: Generation and Reaction with Arenes
  • Ene Reaction of 1,3-Dehydro-ο-Carborane
  • Cage Boron Arylation of ο-Carborane via Metal-Free, Visible-Light-Mediated Radical Coupling
  • Conclusion
  • Experimental Section.

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